- Nick D
Isotopically Enriched Cubic Boron Nitride Reveals High Thermal Conductivity
An international team of physicists, materials scientists, and mechanical engineers has confirmed the high thermal conductivity predicted in isotopically enriched cubic boron nitride, the researchers report in the advance electronic edition of the journal Science.
The thermal conductivity of a material conveys how much heat can pass through it when its ends are at different temperatures. Materials with very high thermal conductivity have important technological applications, such as cooling microelectronics. But very few of them have been discovered.
Theoreticians had predicted that isotopically pure cubic boron nitride (c-BN), should have extremely high thermal conductivity—second only to crystals made out of carbon, such as diamond.
"We wanted to determine whether high quality c-BN can in fact be made to observe the large thermal conductivity magnitudes in c-BN, and whether the huge increase in thermal conductivity with isotopic purification predicted from theoretical calculations is measured in the real material," said Boston College Professor of Physics David Broido, a co-author of the report.
c-BN is particularly challenging to make. Also, it is difficult to measure the thermal conductivity accurately when the value is high. The team overcame these challenges, and the measured thermal conductivity values for the c-BN samples were quite close to the ones they had calculated.
"The study confirms c-BN as one of only a handful of ultrahigh thermal conductivity materials, and shows it to have the largest increase in its thermal conductivity upon isotopic enrichment ever observed," Broido said.
The team also studied the related compounds, boron phosphide (BP) and boron arsenide (BAs). Most elements in nature have mixtures of isotopes, Broido explained. For example, naturally occurring boron has two isotopes, approximately 20 percent boron-10 and 80 percent boron-11. These different isotopes throughout the material produce disorder that adds to the thermal resistance. By making the material with only one isotope (either just B-10 or just B-11) through isotopic enrichment, this resistance is reduced so the thermal conductivity increases, he said.
By a remarkable coincidence of nature, the elements nitrogen, phosphorus and arsenic, which naturally bond with boron to make c-BN, BP and BAs, have only a single isotope. So, for these compounds the isotopic disorder is only on the boron atoms and thus is the same in all three compounds made with naturally occurring boron, Broido said. Yet, isotopic enrichment of the boron atoms gave a doubling of thermal conductivity for c-BN, but much smaller increases for BP and BAs.
The boron and nitrogen atoms have roughly the same mass, while arsenic and phosphorous are heavier.
"We showed that the larger arsenic and phosphorous masses compared with boron caused the isotopic disorder in BAs and BP to give only small resistance to heat flow," said Broido, who performed theoretical calculations with Boston College post-doctoral fellow Navaneetha K. Ravichandran. "It is as if the isotopic disorder becomes invisible to the heat flowing through the BAs and BP samples."
In contrast, removing the same amount of disorder through isotopic enrichment in c-BN results in a huge increase in thermal conductivity.
In all, 24 researchers contributed to the project. In addition to Boston College, the team included the research groups of Gang Chen at MIT, David Cahill at the University of Illinois, Urbana-Champaign, Li Shi at the University of Texas in Austin, Bing Lv at University of Texas in Dallas, Zhifeng Ren at the University of Houston, and Takashi Taniguchi at Japan's National Institute for Materials Science.
"It was amazing to see the measured data and theoretical calculations consistently agreeing so closely with each other. The theory has no parameters in it that can be adjusted to fit the measurements. It either agrees with the measurements or it doesn't," said Broido. "The excellent agreement highlights the accuracy of the theory, the precision of the measurements, and the high purity of the samples."
Broido said further investigation is needed to better understand the types of defects that occur in c-BN that act to reduce its heat conductivity. Because such ultrahigh thermal conductivity materials are so rare, he hopes that theoretical and computational searches can identify new candidates and unravel the mysteries surrounding their usual properties.